Effective removal of Hymexazol pesticide from polluted water using cadmium oxide nanoparticles prepared by photolysis methods: Thermodynamic, kinetic, and isothermal studies
DOI:
https://doi.org/10.5281/zenodo.10269432Keywords:
Adsorption, Cadmium Oxide nanopartical, Hymexazol, Pesticide, Nanotechnology, Water contaminationAbstract
The problem of water pollution with pesticides is one of the most dangerous types of pollution, as it is considered one of the most important causes of cancer for humans, as well as the destruction of the aquatic environment. Currently, several techniques have been used to solve this problem, the most prominent of which is the adsorption technique. The purpose of this study is to investigate the removal of hymexazol pesticide from an aqueous solution by using a cadmium oxide nanopartical adsorbent. CdO NPs were prepared by the photolysis method, and they were characterized by several characterization techniques, such as XRD, TEM, and FE-SEM. Batch adsorption experiments were performed using a variety of factors, such as contact time, adsorbent dose, initial pesticide concentration, and temperature. The results showed that the removal efficiency of hymexazol pesticide on CdO NPs was the highest at a contact time of 50 minutes. The equilibrium data were well fitted with Freundlich mode. The kinetic investigations reveal that the pseudo-second-order model can describe hymexazol pesticide adsorption processes. According to the thermodynamic study, hymexazol pesticide adsorption is a physisorption-endothermic and spontaneous process.
References
Abdullah, T. A. (2022). Functionalized multi-walled carbon nanotubes for oil spill cleanup from water. Clean Technologies and Environmental Policy, 24(2), 519-541.
Abla, F. (2023). Chapter 12 - Nanotechnology for the removal of pesticides hazardous to human health. In Nanotechnology in Biomedicine (pp. 333-361).
Adegoke, K. A. (2023). Bibliometric evaluation of nanoadsorbents for wastewater treatment and way forward in nanotechnology for clean water sustainability. Scientific African, 21, e01753.
Aguilar-Pérez, K. M. (2022). Nano-sorbent materials for pharmaceutical-based wastewater effluents - An overview. Case Studies in Chemical and Environmental Engineering, 2, 100028.
Ahadi, N. (2022). Facile synthesis of hierarchically structured MIL-53 (Al) with superior properties using an environmentally-friendly ultrasonic method for separating lead ions from aqueous solutions. Scientific Reports, 1-17.
Al-Ghouti, M. A. (2020). Guidelines for the use and interpretation of adsorption isotherm models: A review. Journal of hazardous materials, 122383.
Al-Ghouti, M. A. (2020). Mechanistic understanding of the adsorption and thermodynamic aspects of cationic methylene blue dye onto cellulosic olive stones biomass from wastewater. Scientific Reports, 10(1), 1-18.
Alhares, H. S. (2023). Sunflower Husks Coated with Copper Oxide Nanoparticles for Reactive Blue 49 and Reactive Red 195 Removals: Adsorption Mechanisms, Thermodynamic, Kinetic, and Isotherm Studies. Water, Air, & Soil Pollution, 1(35), 234.
Ali, N. S. (2022). Adsorption of methyl violet dye onto a prepared bio-adsorbent from date seeds: Isotherm, kinetics, and thermodynamic studies. Heliyon, 8(8).
Aragaw, T. A. (2022). A comparative study of acidic, basic, and reactive dyes adsorption from aqueous solution onto kaolin adsorbent: Effect of operating parameters, isotherms, kinetics, and thermodynamics. Emerging Contaminants, 59-74.
Ashmawy, A. M. (2023). Novel kappa-carrageenan− poly (vinyl alcohol)− modified pumice Hydrogel composite for the adsorption of cationic dye. Egyptian Journal of Chemistry, 66(12), 21-35.
Balci, B. (2022). Sequential Fe2O3-Powdered Activated Carbon/Activated Sludge Process for the Removal of Reactive Black 5 and Chemical Oxygen Demand from Simulated Textile Wastewater. International Journal of Environmental Research, 11.
Batool, F. (2023). Removal of Cd (II) and Pb (II) from synthetic wastewater using Rosa damascena waste as biosorbent: An insight into adsorption mechanisms, kinetics, and thermodynamic studies. Chemical Engineering Science, 229072.
Boher, S. (2023). Metal doped nanocomposites for detection of pesticides and phenolic compounds by colorimetry: Trends and challenges. OpenNano, 100168.
Bukhari, A. (2023). Introduction of CdO nanoparticles into graphene and graphene oxide nanosheets for increasing adsorption capacity of Cr from wastewater collected from petroleum refinery. Arabian Journal of Chemistry, 16(2), 104445.
Chen, P. (2023). Selective removal of heavy metals by Zr-based MOFs in wastewater: New acid and amino functionalization strategy. Journal of Environmental Sciences, 268-280.
Chowdhary, P. (2020). Role of industries in water scarcity and its adverse effects on environment and human health. Environmental Concerns and Sustainable Development: Volume 1: Air, Water and Energy Resources, 335-256.
Dugan, S. T. (2023). A combined approach for the estimation of groundwater leaching potential and environmental impacts of pesticides for agricultural lands. Science of The Total Environment, 901, 165892.
Hassan, N. H. (2023). The potential mechanism underlying the hepatorenal toxicity induced by hymexazol in rats and the role of NF‐κB signaling pathway. Journal of Biochemical and Molecular Toxicology, e23304.
Hassanen, E. I. (2022). A Comprehensive Study on the Mechanistic Way of Hexaflumuron and Hymexazol Induced Neurobehavioral Toxicity in Rats. Neurochemical Research, 47(10), 3051-3062.
How, C.-K. (2022). Adsorption properties of β-carotene on mesoporous carbon-coated honeycomb monolith: Kinetics, thermodynamics, and regeneration studies. Korean Journal of Chemical Engineering, 39(11), 3109-3120.
Kamil, A. F. (2021). Cibacron red dye removal in aqueous solution using Synthesized CuNiFe2O5 Nanocomposite: Thermodynamic and kinetic studies. Egyptian Journal of Chemistry, 64(11), 6133-6145.
Kishore, K. (2023). Technological challenges in nanoparticle-modified geopolymer concrete: A comprehensive review on nanomaterial dispersion, characterization techniques and its mechanical properties. Case Studies in Construction Materials, 19, e02265.
Korotcenkov, G. (2023). II-VI Wide-Bandgap Semiconductor Device Technology: Stability and Oxidation. In Handbook of II-VI Semiconductor-Based Sensors and Radiation Detectors: Volume 1, Materials and Technology (pp. 517-550).
Kumar, N. (2023). Hydrogel Nanocomposite Adsorbents and Photocatalysts for Sustainable Water Purification. Advanced Materials Interfaces, 10(2), 1201375.
Mondal, P. (2023). Sustainable application of nanoparticles in wastewater treatment: Fate, current trend & paradigm shift. Environmental Research, 232, 116071.
Mondol, M. M. (2020). Adsorptive removal of pesticides from water with metal–organic framework-based materials. Chemical Engineering Journal, 441, 129688.
Nagrath, L. (2023). Nanomaterials in Wastewater Management. In Advanced Application of Nanotechnology to Industrial Wastewater (Vol. 236, pp. 279-297).
Nguyen, C. T. (2023). Paraquat removal by free and immobilized cells of Pseudomonas putida on corn cob biochar. Case Studies in Chemical and Environmental Engineering, 8, 100376.
Patel, H. (2022). Comparison of batch and fixed bed column adsorption: a critical review. International Journal of Environmental Science and Technology, 10409-10426.
Qi, X. (2021). Recent advances in polysaccharide-based adsorbents for wastewater treatment. Journal of Cleaner Production, 128221.
Raghu, M. S. (2021). Simple in-situ functionalization of polyaniline with boroncarbonitride as potential multipurpose photocatalyst: Generation of hydrogen, organic and inorganic pollutant detoxification. Nano-Structures & Nano-Objects, 25, 100667.
Rai, P. K. (2023). Role of Water-Energy-Food Nexus in Environmental Management and Climate Action. Energy Nexus, 100230.
Shahi Khalaf Ansar, B. (2022). Removal of organic and inorganic contaminants from the air, soil, and water by algae. Environmental Science and Pollution Research, 1-29.
Shimi, A. K. (2022). Green synthesis of SrO nanoparticles using leaf extract of Albizia julibrissin and its recyclable photocatalytic activity: an eco-friendly approach for treatment of industrial wastewater. Environmental Science: Advances, 1(5), 849-861.
Trellu, C. (2021). Electrochemical technologies for the treatment of pesticides. Current Opinion in Electrochemistry, 26, 100677.
Wekoye, J. N. (2020). Kinetic and equilibrium studies of Congo red dye adsorption on cabbage waste powder. Environmental Chemistry and Ecotoxicology, 2, 24-31.
Yousfi, A. (2022). Bifenthrine & Hymexazol Toxic Effects on Helix aspersa and the Evaluation of the Protective Effect of Orange Essential Oils. Annals of the Romanian Society for Cell Biology, 26(01), 3270-3284.
Zair, Z. R. (2022). Optimization, equilibrium, kinetics and thermodynamic study of congo red dye adsorption from aqueous solutions using Iraqi porcelanite rocks. Heat and Mass Transfer, 58(8), 1393-1410.
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